How and Why to Decant a Wine

Why and How to decant a wine ? Here are the answers.
Decanting is all about removing sediment from a wine, and allowing the wine to breathe. These are things that older, red wines do - young wines and white wines do not usually have to be decanted.
First, the sediment. Wines have all sorts of organic things in them - yeast, grape skins, and so on. The wine naturally has very small particles of these things that, over the years that wine age, settle out of the wine. That's why with older red wines, which have much more skin contact, you get more sediment.
The trick is to pour the wine slowly into the decanter, keeping the same side down that was down during the aging process. You don't want to mix all that sediment in now! Be sure not to let the sediment end up in the decanting glass. Some people, with a bottle full of sediment (i.e. an old port), pour "over a candle". The candle just helps you see the sediment in the bottle neck better as it begins to slide towards the opening.
OK, now you have a wine without sediment in it. Why would you let it sit there? Isn't wine and air a bad combination? Well, yes and no. Yes, during the years of aging you don't want air getting to the wine. However, now that you're about to drink it, air getting across a good surface area of a wine can bring out its aromas.
There is of course a point at which the air causes more damage than good. If you let the wine sit out for say 8 hours, it warms up to your ambient room temperature which in modern times is 23°C or more, which is awful for wine flavor. When the French talked of Room Temperature in the 1800s, they meant in the 18°C! Also, wine + air = vinegar. If you let it sit there for over 8 hours, the vinegar flavors are going to overpower any nice flavors the wine had, as it goes through this conversion. If you don't finish the wine over the course of your meal or discussion, seal the rest up and put it into the fridge.
This is true for vintage ports as well. While the port is fortified, it is still a delicate wine and not meant for a lot of air contact. You really can taste the flavor difference in a port that's been left open for too long.
Note that just taking a cork out of a bottle does very little as far as "breathing". The tiny amount of surface area touching the air in the bottle neck will cause no real change in the wine over even a few hours. You want a decanter that creates a lot of surface air, for the wine to interact with that air.

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